If you plan to wear gloves, put them on before handling the dried peppers. Over a sink, plate, or garbage can, pull the stems off the dried peppers and open them up. Toss the stems and remove all of the seeds as well. Once cleaned, rip the peppers into smaller pieces for toasting and set aside. Measure out the cumin and black peppercorns and set those aside as well.
First, toast the peppers in a sauté pan, small pot, or in your Dutch oven on medium. Use tongs to move the peppers around and flip them while toasting. When the peppers become fragrant (1-3 minutes), move them to the blender. Then, toast the cumin and the peppercorns, the same way as the peppers, until you can smell them (another 1-3 minutes). Pour the toasted spices into the blender with the peppers. Next, pour 1½ cups (.4L) of chicken stock into the small pot, sauté pan, or the Dutch oven and turn the heat to medium/medium-high, to bring it to a low boil.
When the stock boils, pour it over the peppers and spices and push the spices under the liquid line to hydrate. Add the garlic cloves, anchovy, marmite, molasses, mushroom powder, achiote (annatto) paste, tamari (or soy sauce), natural cocoa powder, and tomato paste to the blender while the peppers soak. After about 15-20 minutes of the peppers rehydrating, all of the other ingredients should be added and it’s time to blend the paste.
Blend everything and scoop the chili paste into a bowl for later use. If it looks like more liquid is needed to blend, add a little more of the chicken stock to loosen it up. (the paste gets cooked again a bit later, so it’s important that it remains thick. Don’t add too much.)
Next, remove the stem and seeds to the poblano pepper and small dice the pepper. Set the pieces aside and small dice the onion as well. Lastly, prep the chuck roast by removing any large pieces of fat or silver skin. It’s okay if it produces smaller or oblong pieces of roast. Once trimmed, slice the chuck roast into ¾-1 in (2-2.5cm) strips. Pat the pieces dry and lightly coat them in 1 tbsp of neutral oil and 1 tsp (2.4g) kosher salt. Set those aside as well.
At this point, the paste, veggies, and meat should be ready. Measure out the oregano and the rest of the chicken stock and open the can of crushed tomatoes. Set them with the rest of the chili components. Time to start cooking.
Place an enameled Dutch oven on your stove top. Turn the burner to medium/high heat and add in the rest of the neutral oil. Working in batches, add 3-4 pieces of chuck roast to the heated pot. Let the meat sear until the side touching the bottom of the pot browns and releases from the pot’s surface. Flip the pieces of meat to all sides until they are all seared. Remove the chuck and add in the next batch. Repeat the searing process until all of the beef has been browned. (If any browned bits develop on the bottom of the pot and look or smell like they are getting close to burning, pour some of the water 1 tbsp (15ml) at a time into the pot where it’s getting dark. Scrape the fond (browned bits) up or move the meat around to collect it.) Set the seared meat aside once again.
Next, turn the heat down and add the paste into the Dutch oven. Scrape it around the pot with a flat-bottomed spatula for 1-2 minutes. The paste should cook and darken a bit before it also begins to stick to the pot. Toss in the diced onion and sprinkle about ½ tsp (1.2g) of kosher salt over the top, while stirring and scraping. Once the onions begin to soften, add in the poblano pepper and the oregano and stir those around for another 4-5 minutes or so. (At any point, if the bottom is in jeopardy of burning, even with the aromatics added, pour a little bit of water where it’s too dark and scrape.)
Fully deglaze the pot with the rest of the chicken stock and scrape the bottom of the pot until ALL of the fond built up there comes up and incorporates into the sauce. (Any food left stuck to the bottom of the pot will burn over the course of cooking, even with liquid in the pot, so make sure you are thorough.) Lower the stovetop temperature to medium-low and pour in the tomatoes.
Next, cut the seared and rested chuck roast into bit sized pices. It’s up to you for how big you would like them to be. I prefer ½in (1.3cm) chunks. Then, add in seared meat and any liquid that escaped the beef during resting.
At this point, open the cans of beans. Place a colander in the sink and use it to strain and rinse them. Once cleaned, dump the beans into the chili. Then, measure and add in the apple cider vinegar and masa harina. Give the chuck roast chili a good mix, lower the temp a bit, cover the pot with a lid, and let it come to a simmer for 30 minutes. After the bit of time cooking, give the chili a taste and add any additonal salt or balancing ingredients to taste. (see FAQs for balancing flavor). Re-cover the chili and let it cook for another 1.5-2 hours. When the meat has softened but stays intact, add in the vodka (optional) stir and simmer for another 10 minutes before serving.